H.I.V.E Five (2003) vs Super Villain Girls (2019)
And since I did the hero teams, I might as well do the villain teams as well. The rules and rounds will be the same as the hero one, and here are the combinations of Round 1.
Jinx vs Catwoman
Gizmo vs Star Sapphire
Mammoth vs Giganta
See-More vs Poison Ivy
Billy Numerous vs Harley Quinn
Kyd Wykkyd vs Livewire